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If one face has a lower mana value and the other doesn't, you can only cast the spell on that first face

Gambit also has the added benefit of potentially letting you flip a lot of coins in coin flip decks specifically

Secondly, it allows players to team up their favourite characters without also dropping them into the larger pool of Partnered Commanders, where they could more easily be broken wide open by unexpected synergies

There is no shortage of ways to do so in decks that play Heartfire Hero, and if not removed early, can often win you the game

As such, Im of the opinion that hes probably best used in a deck focused around dealing direct damage and cards such as Curiosity